Peculiarities of the porous structure of aluminosilicate mesoporous substances obtained in the presence of biotemplates

被引:2
作者
Smelaya, ZV [1 ]
Matkovskaya, LA [1 ]
Goltsov, YG [1 ]
机构
[1] Natl Acad Sci Ukraine, LV Pisarzhevsky Phys Chem Inst, UA-03039 Kiev, Ukraine
关键词
biomimetic chemistry; biomineralization; glucose oxidase; Kelvin equation; lecithin; mesoporous aluminosilicates; methanol ad(de)sorption isotherm; porous structure;
D O I
10.1023/A:1010198400353
中图分类号
O414.1 [热力学];
学科分类号
摘要
Supramolecular structures of lecithin occurred to be the template in the synthesis of mesoporous aluminosilicates; using of various combinations of lecithin and cetyltrimethyl-ammonium bromide or octadecylamine as templating agents allowed to obtain mesoporous substances with pores up to 100 Angstrom, as well as biporous materials in aluminosilicate system. In the presence of glucose oxidase and cetyltrimethyl-ammonium bromide combinations aluminosilicate substances with complex porous structure were shown to be formed (pore size distributions exhibited 3 peaks, corresponding 3 effective size of mesopores in the 30-100 Angstrom range). The investigation of sorption of glucose oxidase on obtained aluminosilicate mesoporous substances was carried out, the results obtained allow us to consider such materials as prospect for creation high capable and selective sorbents for biomolecules sorption, as well as active elements of chemical and biosensors.
引用
收藏
页码:443 / 450
页数:8
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