The future of aluminum chemistry

被引:60
作者
Atwood, DA [1 ]
Yearwood, BC [1 ]
机构
[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
关键词
aluminum; catalysis; materials; biological;
D O I
10.1016/S0022-328X(00)00147-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This article represents a survey of current aluminum chemistry and some predictions regarding what type of aluminum chemistry will be conducted in the year 2000 and after. Because of the abundance and availability of aluminum in the earth, research incorporating this element will always be of importance to applications that impact on daily life. Indeed, applied chemistry is the primary goal of most aluminum research. It is likely that three broad areas of aluminum chemistry, catalysis, materials synthesis, and biological studies, will see substantial activity in the future. The use of aluminum in materials will continue in step with the growth of materials science, in general. In contrast, the use of aluminum compounds in catalysis and in effecting synthetic transformations will see a spectacular increase. This is a result of an increased understanding of the chemistry of aluminum, and the availability of a wide range of compounds containing aluminum, which has been achieved over the past few decades during a period of increased attention to Main Group chemistry. In the coming years a clear understanding of the influence of aluminum on biological systems will almost certainly be obtained based upon the quality and amount of effort that has focused on this area in recent times. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:186 / 197
页数:12
相关论文
共 178 条
[1]   Methylmethacrylate complexes of sterically hindered aluminum aryloxides: activation of methacrylic esters [J].
Akakura, M ;
Yamamoto, H ;
Bott, SG ;
Barron, AR .
POLYHEDRON, 1997, 16 (24) :4389-4392
[2]   SEMICONDUCTOR NANOCRYSTALS [J].
ALIVISATOS, AP .
MRS BULLETIN, 1995, 20 (08) :23-32
[3]  
[Anonymous], 1930, ALUMINUM ITS PRODUCT
[4]   Neutral anion receptors: design and application [J].
Antonisse, MMG ;
Reinhoudt, DN .
CHEMICAL COMMUNICATIONS, 1998, (04) :443-448
[5]  
APPANNA VD, 1995, BIOMETALS, V8, P142
[6]   Factors affecting cation formation in group 13 alkyl halide complexes [J].
Atwood, D ;
Jegier, J .
CHEMICAL COMMUNICATIONS, 1996, (13) :1507-1508
[7]   Structural characterization of the unusual adduct complex Me(2)Bu(t)Al-NH[Li(thf)(3)](C6H3Pr2i-2,6) [J].
Atwood, D ;
Rutherford, D .
CHEMICAL COMMUNICATIONS, 1996, (10) :1251-1252
[8]   Halide effects in the formation of four-coordinate, cationic aluminum [J].
Atwood, D ;
Jegier, J .
INORGANIC CHEMISTRY, 1996, 35 (15) :4277-4282
[9]   SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(SALPANAL)LI(THF)(2)](2) AND [(SALOMPHANAL)-LI(THF)(2)](2) - A NEW CLASS OF ALUMINUM ANION [J].
ATWOOD, DA ;
RUTHERFORD, D .
INORGANIC CHEMISTRY, 1995, 34 (15) :4008-4010
[10]   Cationic group 13 complexes [J].
Atwood, DA .
COORDINATION CHEMISTRY REVIEWS, 1998, 176 :407-430