Production and LDMS characterisation of endohedral alkali-fullerene films

被引：72

作者：

Campbell, EEB

Tellgmann, R

Krawez, N

Hertel, IV

机构：

[1] Max Born Inst Nichtlineare Opt & Kurzzeitspektros, D-12474 Berlin, Germany

[2] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1997年 / 58卷 / 11期

关键词：

D O I：

10.1016/S0022-3697(97)00063-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thin films of C-60 in which up to 50% of the fullerenes contain an alkali ion have ben produced by irradiating successive monolayers of C-60 with an ion beam of appropriate energy. The films have been characterised by laser desorption mass spectrometry. They are stable in air and the endohedral fullerenes can be sublimed. The efficiency of the production method is much higher than any other available method for producing endohedral fullerenes and should be generally applicable to other endohedral species. (C) 1997 Elsevier Science Ltd.

引用

收藏

页码：1763 / 1769

页数：7

相关论文

共 13 条

[1] ATOMS IN CARBON CAGES - THE STRUCTURE AND PROPERTIES OF ENDOHEDRAL FULLERENES [J].

BETHUNE, DS ;

JOHNSON, RD ;

SALEM, JR ;

DEVRIES, MS ;

YANNONI, CS .

NATURE, 1993, 366 (6451) :123-128

[2] COLLISION ENERGY-DEPENDENCE OF HE AND NE CAPTURE BY C-60(+) [J].

CAMPBELL, EEB ;

EHLICH, R ;

HIELSCHER, A ;

FRAZAO, JMA ;

HERTEL, IV .

ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1992, 23 (01) :1-2

[3] FULLERENES WITH METALS INSIDE [J].

CHAI, Y ;

GUO, T ;

JIN, CM ;

HAUFLER, RE ;

CHIBANTE, LPF ;

FURE, J ;

WANG, LH ;

ALFORD, JM ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7564-7568

[4] LANTHANUM COMPLEXES OF SPHEROIDAL CARBON SHELLS [J].

HEATH, JR ;

OBRIEN, SC ;

ZHANG, Q ;

LIU, Y ;

CURL, RF ;

KROTO, HW ;

TITTEL, FK ;

SMALLEY, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7779-7780

[5] HE CAPTURE BY NEGATIVELY CHARGED BUCKMINSTERFULLERENE [J].

KLEISER, R ;

SPRANG, H ;

FURRER, S ;

CAMPBELL, EEB .

ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1993, 28 (02) :89-90

[6] STABLE COMPOUNDS OF HELIUM AND NEON - HE-AT-THE-COST-OF-C60 AND NE-AT-THE-COST-OF-C60 [J].

SAUNDERS, M ;

JIMENEZVAZQUEZ, HA ;

CROSS, RJ ;

POREDA, RJ .

SCIENCE, 1993, 259 (5100) :1428-1430

[7] INCORPORATION OF HELIUM, NEON, ARGON, KRYPTON, AND XENON INTO FULLERENES USING HIGH-PRESSURE [J].

SAUNDERS, M ;

JIMENEZVAZQUEZ, HA ;

CROSS, RJ ;

MROCZKOWSKI, S ;

GROSS, ML ;

GIBLIN, DE ;

POREDA, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) :2193-2194

[8] Chromatographic fractionation of fullerenes containing noble gas atoms [J].

Saunders, M ;

Khong, A ;

Shimshi, R ;

JimenezVazquez, HA ;

Cross, RJ .

CHEMICAL PHYSICS LETTERS, 1996, 248 (1-2) :127-128

[9] COLLISIONAL ENERGY-DEPENDENCE OF HE CAPTURE BY INTERNALLY EXCITED C-60 ANIONS [J].

SPRANG, H ;

MAHLKOW, A ;

CAMPBELL, EEB .

CHEMICAL PHYSICS LETTERS, 1994, 227 (1-2) :91-97

[10] Endohedral fullerene production [J].

Tellgmann, R ;

Krawez, N ;

Lin, SH ;

Hertel, IV ;

Campbell, EEB .

NATURE, 1996, 382 (6590) :407-408