Cyclometallated Iridium Complexes as Sensitizers for Dye-Sensitized Solar Cells

被引：68

作者：

Baranoff, Etienne ^{[1
]}

Yum, Jun-Ho ^{[1
]}

Jung, Il ^{[1
]}

Vulcano, Rosaria ^{[1
]}

Graetzel, Michael ^{[1
]}

Nazeeruddin, Md. Khaja ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol, Sch Basic Sci, Inst Chem Sci & Engn,Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 03期

关键词：

cyclometallation; iridium; charge transfer; sensitizers; solar cells; NANOCRYSTALLINE TITANIUM-DIOXIDE; TRANSITION-METAL-COMPLEXES; ELECTRON-TRANSFER; CHARGE-SEPARATION; POLYPYRIDINE COMPLEXES; ORGANIC SENSITIZERS; BIS-TERPYRIDINE; LIGHT; EFFICIENCY; STATE;

D O I：

10.1002/asia.200900429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New sensitizers based on cyclometallated iridium (III) complexes have been studied. Despite poor absorption properties, efficiencies up to 2.5 % were observed. It was seen that poor light-harvesting properties of the dyes are the main reasons for those efficiencies, which may be improved with better light-absorbing ligands. Electron-dynamic investigations show that very fast processes are taking place. (Figure presented). © 2010 Wiley-VCH Verlag GmbH&Co. KGaA.

引用

收藏

页码：496 / 499

页数：4

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