A model of normal transfer of electrons on CO+K/Cu(111) surface

被引:2
作者
Li, HY [1 ]
Zhu, L [1 ]
Xu, YB [1 ]
机构
[1] Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China
关键词
work function change; coadsorption; CO+K/Cu(111) surface;
D O I
10.1016/S0169-4332(97)00792-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Co-adsorption of CO and Potassium on Cu(lll) surface was investigated using a Kelvin probe. We found that CO can adsorb on the potassium pre-covered Cu(lll) surface at room temperature. When theta(K) < theta(min) (theta(min) = 0.18), the adsorption of CO makes the work function increase. When theta(K) > theta(min), the work function first decreases and then increases with CO exposure. the results can be well accounted for by jellium-slab model [R.Q. Wu, K.L. Chen, D.S. Wang, Phys. Rev. B 38 (1988) 3180]. A Model of normal transfer of electrons is proposed for the co-adsorption of CO and potassium on the Cu(lll) surface. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:342 / 346
页数:5
相关论文
共 21 条
[1]   HREELS AND ARUPS INVESTIGATION OF THE COADSORPTION OF CO AND K ON CU(111) [J].
BAO, S ;
XU, R ;
XU, CY ;
LI, HY ;
ZHU, L ;
XU, YB .
SURFACE SCIENCE, 1992, 271 (03) :513-518
[2]   MOLECULAR ORBITAL VIEW OF CHEMISORBED CARBON MONOXIDE [J].
BLYHOLDER, G .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (10) :2772-&
[3]   CNDO MODEL OF CARBON-MONOXIDE CHEMISORBED ON NICKEL [J].
BLYHOLDER, G .
JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (07) :756-761
[4]   POTASSIUM ADSORPTION ON FE(110) [J].
BRODEN, G ;
BONZEL, HP .
SURFACE SCIENCE, 1979, 84 (01) :106-120
[5]   POTASSIUM PROMOTED C-O BOND WEAKENING ON RU(001) .1. THROUGH-METAL INTERACTION AT LOW POTASSIUM PRECOVERAGE [J].
DEPAOLA, RA ;
HRBEK, J ;
HOFFMANN, FM .
JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (05) :2484-2498
[6]   HEATS OF CHEMISORPTION ON PROMOTED IRON SURFACES AND ROLE OF ALKALI IN FISCHER-TROPSCH SYNTHESIS [J].
DRY, ME ;
SHINGLES, T ;
BOSHOFF, LJ ;
OOSTHUIZ.GJ .
JOURNAL OF CATALYSIS, 1969, 15 (02) :190-&
[7]   NEW LOOK AT THE MECHANISM FOR ALKALI-METAL PROMOTION [J].
EBERHARDT, W ;
HOFFMANN, FM ;
DEPAOLA, R ;
HESKETT, D ;
STRATHY, I ;
PLUMMER, EW ;
MOSER, HR .
PHYSICAL REVIEW LETTERS, 1985, 54 (16) :1856-1859
[8]   ELECTRONIC-STRUCTURE OF A POISONED TRANSITION-METAL SURFACE [J].
FEIBELMAN, PJ ;
HAMANN, DR .
PHYSICAL REVIEW LETTERS, 1984, 52 (01) :61-64
[9]   PHOTOEMISSION AND ELECTRON-ENERGY-LOSS SPECTROSCOPY INVESTIGATION OF CO+K/CU(100) [J].
HESKETT, D ;
STRATHY, I ;
PLUMMER, EW ;
DEPAOLA, RA .
PHYSICAL REVIEW B, 1985, 32 (10) :6222-6237
[10]   THE INTERACTION RANGE IN ALKALI METAL-PROMOTED SYSTEMS [J].
HESKETT, D .
SURFACE SCIENCE, 1988, 199 (1-2) :67-86