Isolation and structure elucidation of minor carotenoids from annatto (Bixa orellana L.) seeds

被引：41

作者：

Mercadante, AZ ^{[1
]}

Steck, A ^{[1
]}

Pfander, H ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

来源：

PHYTOCHEMISTRY | 1997年 / 46卷 / 08期

关键词：

Bixa orellana; Bixaceae; annatto; carotenoids; dimethyl (9Z,9 ' Z)-6,6 '-diapocarotene-6,6 '-dioate; methyl (9Z)-10 '-oxo-6,10 '-diapocaroten-6-oate; methyl (9Z)-6 '-oxo-6,5 '-diapocaroten-6-oate; dimethyl (9Z)-6,6 '-diapocarotene-6,6 '-dioate; methyl (9Z)-8 '-oxo-6,8 '-diapocaroten-6-oate; methyl (4Z)-4,8-dimethyl-12-oxo-dodecyl-2,4,6,8,10-pentaenoate;

D O I：

10.1016/S0031-9422(97)00462-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

From the seed coat of Bixa orellana fruits, six minor carotenoids and one C-14-carotenoid derivative were isolated by chromatography (CC, TLC, HPLC) and their structures elucidated by means of spectroscopy (UV-visible, MS, H-1 and C-13 NMR). Dimethyl (9Z,9'Z)-6,6'-diapocarotene-6,6'-dioate, methyl (9Z)-10'-oxo-6,10'-diapocaroten-6-oate, methyl (9Z)-6'-oxo-6,5'-diapocaroten-6-oate and methyl (4Z)-4,8-dimethyl-12-oxododecyl-2,4,6,8,10-pentaenoate are new compounds, whereas methyl bixin and methyl (9Z)-8'-oxo-6,8'-diapocaroten-6-oate have previously been found in annatto. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：1379 / 1383

页数：5

共 8 条

[1]

Britton G., 1995, Carotenoids: Spectroscopy, V1B, P13

[2]

Englert G., 1995, CAROTENOIDS, V1B, P147

[3]

*IUPAC COMM NOM OR, 1975, PURE APPL CHEM, V41, P407

[4] TERPENOIDS AND AN APOCAROTENOID FROM SEEDS OF BIXA-ORELLANA [J].

JONDIKO, IJO ;

PATTENDEN, G .

PHYTOCHEMISTRY, 1989, 28 (11) :3159-3162

[5] ELECTRONIC SPECTRA OF CAROTENOIDS AT 77 DEGREES K [J].

KE, B ;

IMSGARD, F ;

KJOSEN, H ;

LIAAENJE.S .

BIOCHIMICA ET BIOPHYSICA ACTA, 1970, 210 (01) :139-&

[6] Isolation of methyl 9'Z-apo-6'-lycopenoate from Bixa orellana [J].

Mercadante, AZ ;

Steck, A ;

RodriguezAmaya, D ;

Pfander, H ;

Britton, G .

PHYTOCHEMISTRY, 1996, 41 (04) :1201-1203

[7] Isolation and identification of new apocarotenoids from annatto (Bixa orellana) seeds [J].

Mercadante, AZ ;

Steck, A ;

Pfander, H .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (04) :1050-1054

[8] A stereochemical study of methylbixin [J].

Zechmeister, L ;

Escue, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1944, 66 :322-330

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