Fused Pyrene-Diporphyrins: Shifting Near-Infrared Absorption to 1.5 μm and Beyond

被引：91

作者：

Diev, Vyacheslav V. ^{[1
]}

Hanson, Kenneth ^{[1
]}

Zimmerman, Jeramy D. ^{[2
,3
]}

Forrest, Stephen R. ^{[2
,3
]}

Thompson, Mark E. ^{[1
]}

机构：

[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

[2] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA

[3] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

关键词：

fused-ring systems; dyes/pigments; organic electronics; porphyrinoids; noncovalent interactions; EXCITATION-ENERGY TRANSFER; PORPHYRIN ARRAYS; MESO-MESO; OPTICAL-PROPERTIES; CROSS-SECTION; IR ABSORPTION; TAPES; BETA; ANTHRACENE; COMPLEXES;

D O I：

10.1002/anie.201002669

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Sticking together: Direct fusion of pyrene rings with diporphyrins can be achieved without prior activation of aromatic rings. This simple method gives pyrene-diporphyrin hybrids (see picture, C (pyrene) red, C (porphyrin) dark blue, N light blue, Zn green) with a high near-infrared (NIR) absorption that reaches the wavelengths required for use in telecommunications. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5523 / 5526

页数：4

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