共 32 条
Fused Pyrene-Diporphyrins: Shifting Near-Infrared Absorption to 1.5 μm and Beyond
被引:91
作者:
Diev, Vyacheslav V.
[1
]
Hanson, Kenneth
[1
]
Zimmerman, Jeramy D.
[2
,3
]
Forrest, Stephen R.
[2
,3
]
Thompson, Mark E.
[1
]
机构:
[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA
[2] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA
[3] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA
关键词:
fused-ring systems;
dyes/pigments;
organic electronics;
porphyrinoids;
noncovalent interactions;
EXCITATION-ENERGY TRANSFER;
PORPHYRIN ARRAYS;
MESO-MESO;
OPTICAL-PROPERTIES;
CROSS-SECTION;
IR ABSORPTION;
TAPES;
BETA;
ANTHRACENE;
COMPLEXES;
D O I:
10.1002/anie.201002669
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Figure Presented) Sticking together: Direct fusion of pyrene rings with diporphyrins can be achieved without prior activation of aromatic rings. This simple method gives pyrene-diporphyrin hybrids (see picture, C (pyrene) red, C (porphyrin) dark blue, N light blue, Zn green) with a high near-infrared (NIR) absorption that reaches the wavelengths required for use in telecommunications. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5523 / 5526
页数:4
相关论文