Fused Pyrene-Diporphyrins: Shifting Near-Infrared Absorption to 1.5 μm and Beyond

被引:91
作者
Diev, Vyacheslav V. [1 ]
Hanson, Kenneth [1 ]
Zimmerman, Jeramy D. [2 ,3 ]
Forrest, Stephen R. [2 ,3 ]
Thompson, Mark E. [1 ]
机构
[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA
[2] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA
[3] Univ Michigan, Dept Phys, Ann Arbor, MI 48109 USA
关键词
fused-ring systems; dyes/pigments; organic electronics; porphyrinoids; noncovalent interactions; EXCITATION-ENERGY TRANSFER; PORPHYRIN ARRAYS; MESO-MESO; OPTICAL-PROPERTIES; CROSS-SECTION; IR ABSORPTION; TAPES; BETA; ANTHRACENE; COMPLEXES;
D O I
10.1002/anie.201002669
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Sticking together: Direct fusion of pyrene rings with diporphyrins can be achieved without prior activation of aromatic rings. This simple method gives pyrene-diporphyrin hybrids (see picture, C (pyrene) red, C (porphyrin) dark blue, N light blue, Zn green) with a high near-infrared (NIR) absorption that reaches the wavelengths required for use in telecommunications. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5523 / 5526
页数:4
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