Unusual oxidation of an N-heterocycle ligand in a metal-organic framework

被引：50

作者：

Han, Zhangang

Zhao, Yulong

Peng, Jun ^{[1
]}

Gomez-Garcia, Carlos J.

机构：

[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Key Lab Polyoxometalate Sci,Minist Educ, Changchun 130024, Peoples R China

[2] Hebei Normal Univ, Coll Chem & Mat Sci, Hebei 050016, Peoples R China

[3] Univ Valencia, Inst Mol Sci, Valencia, Spain

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 14期

关键词：

D O I：

10.1021/ic700432p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An in situ ligand reaction from the pyridine cycle to -COO- in the copper-organic framework is achieved under hydrothermal conditions. Compound [Cu-2(bpa)(4)] [1; bpa = 5-(4-bromophenyl)picolinic acid] exhibits a one-dimensional chain architecture based on weak Cu-O interactions. The mechanism of ligand transformation is discussed.

引用

页码：5453 / 5455

页数：3

共 55 条

[1] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[2] New mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes formed by metal-assisted hydrolysis of 3,6-di-2-pyridyl-1,2,4,5-tetrazine (DPTZ): Crystal structures and magnetic properties [J].

Bu, XH ;

Liu, H ;

Du, M ;

Zhang, L ;

Guo, YM ;

Shionoya, M ;

Ribas, J .

INORGANIC CHEMISTRY, 2002, 41 (07) :1855-1861

[3] COPPER(II)-ASSISTED HYDROLYSIS OF 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE .1. CRYSTAL-STRUCTURES OF [BIS(2-PYRIDYLCARBONYL)AMIDO](2-PYRIDYLFORMAMIDE)-COPPER(II) PERCHLORATE MONOHYDRATE AND [BIS(2-PYRIDYLCARBONYL)AMIDO]-COPPER(II) PERCHLORATE [J].

CANTARERO, A ;

AMIGO, JM ;

FAUS, J ;

JULVE, M ;

DEBAERDEMAEKER, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (08) :2033-2039

[4] COPPER(II)-ASSISTED HYDROLYSIS OF 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE .3. CRYSTAL-STRUCTURES OF DIAQUA[BIS(2-PYRIDYLCARBONYL)AMIDO]COPPER(II) NITRATE DIHYDRATE AND AQUABIS(PYRIDINE-2-CARBOXAMIDE)COPPER(II) NITRATE MONOHYDRATE [J].

CASTRO, I ;

FAUS, J ;

JULVE, M ;

AMIGO, JM ;

SLETTEN, J ;

DEBAERDEMAEKER, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :891-897

[5]

Che CM, 2000, ANGEW CHEM INT EDIT, V39, P4084, DOI 10.1002/1521-3773(20001117)39:22<4084::AID-ANIE4084>3.3.CO

[6]

2-E

[7] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].

Chen, Xiao-Ming ;

Tong, Ming-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170

[8] Fluorine-containing donor-acceptor complex:: Infinite chain formed by oxygen•••iodine interaction [J].

Chu, QL ;

Wang, ZM ;

Huang, QC ;

Yan, CH ;

Zhu, SZ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (44) :11069-11070

[9]

Corradi E, 2000, ANGEW CHEM INT EDIT, V39, P1782, DOI 10.1002/(SICI)1521-3773(20000515)39:10<1782::AID-ANIE1782>3.0.CO

[10]

2-5

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