Unusual oxidation of an N-heterocycle ligand in a metal-organic framework

被引：50

作者：

Han, Zhangang

Zhao, Yulong

Peng, Jun ^{[1
]}

Gomez-Garcia, Carlos J.

机构：

[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Key Lab Polyoxometalate Sci,Minist Educ, Changchun 130024, Peoples R China

[2] Hebei Normal Univ, Coll Chem & Mat Sci, Hebei 050016, Peoples R China

[3] Univ Valencia, Inst Mol Sci, Valencia, Spain

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 14期

关键词：

D O I：

10.1021/ic700432p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An in situ ligand reaction from the pyridine cycle to -COO- in the copper-organic framework is achieved under hydrothermal conditions. Compound [Cu-2(bpa)(4)] [1; bpa = 5-(4-bromophenyl)picolinic acid] exhibits a one-dimensional chain architecture based on weak Cu-O interactions. The mechanism of ligand transformation is discussed.

引用

页码：5453 / 5455

页数：3

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