Inorganic-organic hybrid polyoxometalate: Preparation, characterization and electrochemistry properties

被引：55

作者：

Han, ZG ^{[1
]}

Zhao, YL ^{[1
]}

Peng, J ^{[1
]}

Tian, AX ^{[1
]}

Feng, YH ^{[1
]}

Liu, Q ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 05期

基金：

中国国家自然科学基金;

关键词：

inorganic-organic hybrid; polyoxometalate; electrochemistry; carbon paste electrode; electrocatalysis;

D O I：

10.1016/j.jssc.2005.02.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid hybrid material (H(3/4)pbpy)(4)[PMo12O40] center dot 1.25H(2)O (1) (pbpy = 5-phenyl-2-(4-pyridinyl)pyridine) has been prepared and characterized. A structural feature of compound 1 is that the polyoxometalate anions exhibit a one-dimensional inorganic double chain-like structure via weak interactions of O...O. The organic moiety exhibits regular packing with offset aromatic-aromatic interactions between the pbpys, leading to a compact supramolecular framework structure to accommodate the inorganic chains. Compound 1 was employed to fabricate the three-dimensional bulk-modified carbon paste electrode (1-CPE) to research on its electrochemistry properties. The results indicate that 1 retained Keggin molybdate anion electrocatalytic activities toward the reduction of chlorate, hydrogen peroxide and nitrite. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：1386 / 1394

页数：9

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