Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties

被引：63

作者：

Lee, Woo Ram ^{[1
]}

Ryu, Dae Won ^{[1
]}

Lee, Jin Wuk ^{[1
]}

Yoon, Jung Hee ^{[1
]}

Koh, Eui Kwan ^{[2
]}

Hong, Chang Seop ^{[1
]}

机构：

[1] Korea Univ, Dept Chem BK21, Seoul 136713, South Korea

[2] Korea Basic Sci Inst, NanoBio Syst Res Team, Seoul 136713, South Korea

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 11期

关键词：

GAS-ADSORPTION; THERMAL-STABILITY; HYDROGEN STORAGE; H-2; ADSORPTION; CARBON-DIOXIDE; BINDING; AFFINITIES; CATALYSIS; CHANNELS; OXIDE;

D O I：

10.1021/ic902182x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+ to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.

引用

页码：4723 / 4725

页数：3

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