Removal processes of nitric oxide along positive streamers observed by laser-induced fluorescence imaging spectroscopy

被引:32
作者
Hazama, H
Fujiwara, M
Tanimoto, M
机构
[1] Sci Univ Tokyo, Fac Sci & Technol, Dept Elect Engn, Noda, Chiba 2788510, Japan
[2] Electrotech Lab, Tsukuba, Ibaraki 3058568, Japan
关键词
D O I
10.1016/S0009-2614(00)00557-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Removal processes of nitric oxide (NO) in pulsed corona discharges were observed by laser-induced fluorescence (LIF) imaging spectroscopy in a reactor filled with N-2/NO mixtures. Distributions of NO along the streamers and effective energy costs of NO removal (epsilon(rem)) obtained from the LIF images were compared with these predicted by a model taking account of the diffusion. For an initial NO concentration [NO](0) of 1000 ppm epsilon(rem) was 120 +/- 31 eV/molecule, while it was increased up to 620 +/- 160 eV/molecule for [NO](0) of 30 ppm, due to a higher recombination loss of the reducing species of the nitrogen atoms. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:542 / 548
页数:7
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