A new porous three-dimensional lanthanide coordination polymer

被引：182

作者：

Pan, L

Woodlock, EB

Wang, XT

Zheng, C

机构：

[1] Univ Colorado, Dept Chem, Denver, CO 80217 USA

[2] No Illinois Univ, Dept Biochem & Chem, De Kalb, IL 60115 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 18期

关键词：

D O I：

10.1021/ic000209d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The open-framework coordination polymer [Er(C9H9-O-6)(H2O)(2)]. 2.5H(2)O (C9H9O6 = cis,cis-1,3,5-cyclo-hexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C9H9O6)(H2O)(2)]. The metal-organic framework in [Er(C9H9O6)(H2O)(2)] can withstand the removal of I equiv of coordinated water.

引用

页码：4174 / +

页数：6

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