Semiclassical real-time tunneling by multiple spawning of classical trajectories

被引:36
作者
Grossmann, F [1 ]
机构
[1] Tech Univ Dresden, Inst Theoret Phys, D-01062 Dresden, Germany
关键词
D O I
10.1103/PhysRevLett.85.903
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We systematically extend semiclassical real-rime propagation methods based on Gaussian wave packets by using the composition property of the time-dependent quantum-mechanical Green function. For the first time, in an application to the problem of barrier tunneling, a semiclassical time-domain calculation of the transmission probability exhibits good agreement with exact quantum mechanical values at energies below the barrier top. Only two insertions of unity are needed for these results in a benchmark model of reactive scattering.
引用
收藏
页码:903 / 907
页数:5
相关论文
共 17 条
[1]   WIGNERS FUNCTION AND TUNNELING [J].
BALAZS, NL ;
VOROS, A .
ANNALS OF PHYSICS, 1990, 199 (01) :123-140
[2]   FATE OF FALSE VACUUM - SEMICLASSICAL THEORY [J].
COLEMAN, S .
PHYSICAL REVIEW D, 1977, 15 (10) :2929-2936
[3]  
FEYNMAN RP, 1965, QUANTUM MECH PATH IN
[4]   Wave packet correlation function approach to H-2(upsilon)+H->H+H-2(upsilon'): Semiclassical implementation [J].
Garashchuk, S ;
Tannor, D .
CHEMICAL PHYSICS LETTERS, 1996, 262 (3-4) :477-485
[5]   A SEMICLASSICAL CORRELATION-FUNCTION APPROACH TO BARRIER TUNNELING [J].
GROSSMANN, F ;
HELLER, EJ .
CHEMICAL PHYSICS LETTERS, 1995, 241 (1-2) :45-50
[6]  
Grossmann F., 1999, COMMENTS AT MOL PHYS, V34, P141
[7]   A SEMICLASSICAL JUSTIFICATION FOR THE USE OF NON-SPREADING WAVEPACKETS IN DYNAMICS CALCULATIONS [J].
HERMAN, MF ;
KLUK, E .
CHEMICAL PHYSICS, 1984, 91 (01) :27-34
[8]   Semiclassical tunneling in the initial value representation [J].
Kay, KG .
JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (07) :2313-2328
[9]  
KELLER S, 1993, J PHYS B ATOM MOL PH, V26, pL737
[10]   SEMICLASSICAL CORRECTION FOR QUANTUM-MECHANICAL SCATTERING [J].
KESHAVAMURTHY, S ;
MILLER, WH .
CHEMICAL PHYSICS LETTERS, 1994, 218 (03) :189-194