Insights on Adsorption Characterization of Metal-Organic Frameworks: A Benchmark Study on the Novel soc-MOF

被引：138

作者：

Moellmer, J. ^{[1
]}

Celer, E. B. ^{[3
]}

Luebke, R. ^{[2
]}

Cairns, A. J. ^{[2
]}

Staudt, R. ^{[1
]}

Eddaoudi, M. ^{[2
]}

Thommes, M. ^{[3
]}

机构：

[1] Inst Nichtklass Chem eV, D-04318 Leipzig, Germany

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] Quantachrome Instruments, Boynton Beach, FL USA

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2010年 / 129卷 / 03期

关键词：

Adsorption; Characterization; Gas separation; High pressure; MOF; CARBON-DIOXIDE; SURFACE-AREAS; SEPARATION; STORAGE; GAS; CO2;

D O I：

10.1016/j.micromeso.2009.06.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77-323 K) and pressures (0-5 MPa) by using a volumetric low pressure adsorption analyzer equipped with a cryostat, and a high pressure gravimetric system. The advanced interpretation of our systematic adsorption data in combination with the results from a comprehensive structural and surface characterization allows one assessing the potential of these novel MOFs for gas storage and separation applications. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：345 / 353

页数：9

共 35 条

[1] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks [J].