Phase transfer of fluoride ion by phosphonioborins

被引：35

作者：

Agou, Tomohiro

Kobayashi, Junji

Kim, Youngmin

Gabbai, Franqois P. ^{[1
]}

Kawashima, Takayuki

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77840 USA

[2] Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMISTRY LETTERS | 2007年 / 36卷 / 08期

关键词：

D O I：

10.1246/cl.2007.976

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two cationic triarylboranes based on phosphomoborin frameworks have been investigated. Electron-withdrawing phosphonio groups enhanced the Lewis acidity of these boranes which capture fluoride ion in aqueous media and transport it into organic phase.

引用

页码：976 / 977

页数：2

共 17 条

[1] Tuning of the optical properties and Lewis acidity of dibenzopnictogenaborins by modification on bridging main group elements
Agou, Tomohiro
Kobayashi, Junji
Kawashima, Takayuki
[J]. INORGANIC CHEMISTRY, 2006, 45 (22) : 9137 - 9144
[2] Fluoride ion capture from water with a cationic borane
Chiu, Ching-Wen
Gabbai, Francois P.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (44) : 14248 - 14249
[3] Hybrid Lewis acid/hydrogen-bond donor receptor for fluoride
Hudnall, Todd W.
Melaimi, Mohand
Gabbai, Francois P.
[J]. ORGANIC LETTERS, 2006, 8 (13) : 2747 - 2749
[4] Highly functionalized organomagnesium reagents prepared through halogen-metal exchange
Knochel, P
Dohle, W
Gommermann, N
Kneisel, FF
Kopp, F
Korn, T
Sapountzis, I
Vu, VA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) : 4302 - 4320
[5] Fluoride ion complexation by a cationic borane in aqueous solution
Lee, Min Hyung
Agou, Tomohiro
Kobayashi, Junji
Kawashima, Takayuki
Gabbai, Francois P.
[J]. CHEMICAL COMMUNICATIONS, 2007, (11) : 1133 - 1135
[6] Charge-transfer emission in nonplanar three-coordinate organoboron compounds for fluorescent sensing of fluoride
Liu, Xiang Yang
Bai, Dong Ren
Wang, Suning
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (33) : 5475 - 5478
[7] Triaryl boron-based A-π-A vs triaryl nitrogen-based D-π-D quadrupolar compounds for single- and two-photon excited fluorescence
Liu, ZQ
Fang, Q
Cao, DX
Wang, D
Xu, GB
[J]. ORGANIC LETTERS, 2004, 6 (17) : 2933 - 2936
[8] Bidentate group 13 Lewis acids with ortho-phenylene and peri-naphthalenediyl backbones
Melaimi, M
Gabbaï, FP
[J]. ADVANCES IN ORGANOMETALLIC CHEMISTRY, VOL 53, 2005, 53 : 61 - 99
[9] A heteronuclear bidentate Lewis acid as a phosphorescent fluoride sensor
Melaimi, M
Gabbai, FP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) : 9680 - 9681
[10] Structural and electrochemical investigations of the high fluoride affinity of sterically hindered 1,8-bis(boryl)naphthalenes
Melaimi, Mohand
Sole, Stephane
Chiu, Ching-Wen
Wang, Huadong
Gabbai, Francois P.
[J]. INORGANIC CHEMISTRY, 2006, 45 (20) : 8136 - 8143

← 1 2 →