Fluoride ion complexation by a cationic borane in aqueous solution

被引：193

作者：

Lee, Min Hyung

Agou, Tomohiro

Kobayashi, Junji

Kawashima, Takayuki

Gabbai, Francois P. ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 11期

关键词：

D O I：

10.1039/b616814k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phosphonium borane [p-Mes(2)B(C6H4)PMePh2](+) complexes fluoride in water containing 10% methanol with a binding constant of 1.0(+/- 0.1) x 10(3) M-1 to afford the zwitterion p- Mes(2)FB(C6H4) PMePh2.

引用

页码：1133 / 1135

页数：3

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