Synthesis and structural characterisation of the first bis(bora)calixarene:: a selective, bidentate, fluorescent fluoride sensor

被引:106
作者
Arimori, S
Davidson, MG
Fyles, TM
Hibbert, TG
James, TD
Kociok-Köhn, GI
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Victoria, Dept Chem, Victoria, BC V8W 3P6, Canada
关键词
D O I
10.1039/b404937c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.
引用
收藏
页码:1640 / 1641
页数:2
相关论文
共 32 条
  • [1] Multidentate Lewis acids: synthesis, structure and mode of action of a redox-based fluoride ion sensor
    Aldridge, S
    Bresner, C
    Fallis, IA
    Coles, SJ
    Hursthouse, MB
    [J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 740 - 741
  • [2] Trimethyl-aluminium and -gallium derivatives of calix[4]arenes: Cone (mono-metallic) or doubly flattened partial cone (tetrametallic) conformations
    Atwood, JL
    Gardiner, MG
    Jones, C
    Raston, CL
    Skelton, BW
    White, AH
    [J]. CHEMICAL COMMUNICATIONS, 1996, (21) : 2487 - 2488
  • [3] ALUMINUM-FUSED BIS-PARA-TERT-BUTYLCALIX[4]ARENE - A DOUBLE CONE WITH 2 PI-ARENE...H INTERACTIONS FOR INCLUDED METHYLENE-CHLORIDE
    ATWOOD, JL
    BOTT, SG
    JONES, C
    RASTON, CL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (18) : 1349 - 1351
  • [4] Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
  • [5] 2-G
  • [6] CALIXARENE PHOSPHORYLATION - CATION CONTROL OF REACTION PATHWAYS
    BYRNE, LT
    HARROWFIELD, JM
    HOCKLESS, DCR
    PEACHEY, BJ
    SKELTON, BW
    WHITE, AH
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (11) : 1673 - 1683
  • [7] A mixed lithium-strontium polynuclear complex formed within the hexa-deprotonated calix[8]arene framework;: the synthesis and structure of Li4Sr2(H2L)(O2CC4H9)2(dmf)8 [H8L = p-Pri- or p-Bui-calix[8]arene]
    Clague, NP
    Crane, JD
    Moreton, DJ
    Sinn, E
    Teat, SJ
    Young, NA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (20): : 3535 - 3536
  • [8] An insight into ion-transport by calixarenes;: the structure of the dipotassium complex of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent [ethanol/diethylcarbonate (10:1)]
    Clague, NP
    Clegg, W
    Coles, SJ
    Crane, JD
    Moreton, DJ
    Sinn, E
    Teat, SJ
    Young, NA
    [J]. CHEMICAL COMMUNICATIONS, 1999, (04) : 379 - 380
  • [9] Selective fluorescence detection of fluoride using boronic acids
    Cooper, CR
    Spencer, N
    James, TD
    [J]. CHEMICAL COMMUNICATIONS, 1998, (13) : 1365 - +
  • [10] Crystal structure of the molecular addition compound diphenylchloroborane•tetrahydrofuran
    Cross, WI
    Lightfoot, MP
    Mair, FS
    Pritchard, RG
    [J]. INORGANIC CHEMISTRY, 2000, 39 (12) : 2690 - +