Square-pyramidal bonding of I2 molecules at the I- nodes of a polyiodide infinite pseudo-cubic 3D-network

被引：19

作者：

Aragoni, MC

Arca, M

Devillanova, FA

Hursthouse, MB

Huth, SL

Isaia, F

Lippolis, V

Mancini, A

机构：

[1] Univ Cagliari, Dipartimento Chim Inorgan & Analit, I-09042 Cagliari, Italy

[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

CRYSTENGCOMM | 2004年 / 6卷

关键词：

D O I：

10.1039/b415415k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of di-[2]-pyridyl-disulfide (L) with diiodine in molar ratios ranging between 1 : 0.5 and 1 : 5 afforded [(HL+)(I-) . 5/2I(2)] as the only product, containing the first example of a self-assembled infinite polyiodide pseudo-cubic 3D-network featuring distorted square pyramidal I-. 5I(2) moieties at the nodes.

引用

页码：540 / 542

页数：3

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