Photophysical and photocatalytic properties of molybdates and tungstates with a scheelite structure

被引：68

作者：

Kato, H ^{[1
]}

Matsudo, N ^{[1
]}

Kudo, A ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 09期

关键词：

D O I：

10.1246/cl.2004.1216

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Photophysical and photocatalytic properties of molybdates and tungstates with a scheelite structure were investigated. The band gaps of scheelite compounds narrowed when the compounds were composed of Ag+ and Bi3+ ions. (NaBi)(0.5)MoO4 (BG: 3.1 eV) and (AgBi)(0.5)MoO4 (BG: 3.0 eV) showed the photocatalytic activities for O-2 evolution from an aqueous solution containing an electron acceptor. On the other hand, (NaBi)(0.5)-WO4 (BG: 3.5 eV) produced H-2 from an aqueous solution containing an electron donor.

引用

页码：1216 / 1217

页数：2

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