Synthesis, formation and characterization of ZnTiO3 ceramics

被引:100
作者
Chang, YS
Chang, YH [1 ]
Chen, IG
Chen, GJ
Chai, YL
Fang, TH
Wu, S
机构
[1] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
[2] I Shou Univ, Dept Mat Sci & Engn, Kaohsiung 840, Taiwan
[3] Dahan Inst Technol, Dept Resources Engn, Hualien 971, Taiwan
[4] So Taiwan Univ Technol, Dept Mech Engn, Tainan 710, Taiwan
[5] Tung Fang Inst Technol, Dept Elect & Informat Engn, Kaohsiung 821, Taiwan
关键词
powders : solid state reaction; dielectric properties; electrical properties; perovskites;
D O I
10.1016/j.ceramint.2004.01.002
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Zinc titanate (ZnTiO3) powders of perovskite structure were synthesized by conventional solid state reaction using metal oxides. Powders of ZnO and TiO2 in a molar ratio of 1:1 were mixed in a ball mill and then heated at temperatures from 700 to 1000degreesC for various time periods in air. The crystallization temperature of ZnTiO3 powder was similar to820degreesC, activation energy for crystallization was similar to327.14 kJ/mol and for grain growth was similar to48.84 kJ/mol. A transition point was observed when the electrical resistivity was measured versus temperature. Like some ferroelectric materials, a PTCR behavior above the transition temperature was observed with Curie temperature of similar to5 degreesC. (C) 2004 Elsevier Ltd and Techna S.r.l. All rights reserved.
引用
收藏
页码:2183 / 2189
页数:7
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