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Synthesis, crystal structure and luminescent properties of a novel cadmium coordination polymer with unprecedented one-dimensional hetero-triple-stranded chain

被引：52
作者：
Zhou, JH
Peng, YF
Zhang, YP
Li, BL
Zhang, Y
机构：
[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 11期
关键词：
coordination polymer; luminescence; cadmium; bis(benzotriazole) ligand; thiocyanate; triple-stranded chain;
D O I：
10.1016/j.inoche.2004.09.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel cadmium coordination polymer, [Cd-1.5(bbta)(1.5)(NCS)(3)](n) (1) (bbta = 1,2-bis(benzotriazol-1-yl)ethane), possessing the S-bonded octahedral Cd(SCN)(6) and N-bonded octahedral Cd(NCS)(3)(bbta)(3) and unprecedented one-dimensional hetero-triple-stranded chain with alternate two [Cd(NCS)(3)] and one [Cd(bbta)(3)], has been prepared, which exhibits blue luminescent emission at room temperature in the solid state. (C) 2004 Elsevier B.V. All rights reserved.
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收藏
页码：1181 / 1183
页数：3
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