Synthesis, crystal structure and luminescent properties of a novel cadmium coordination polymer with unprecedented one-dimensional hetero-triple-stranded chain

被引：52

作者：

Zhou, JH

Peng, YF

Zhang, YP

Li, BL

Zhang, Y

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 11期

关键词：

coordination polymer; luminescence; cadmium; bis(benzotriazole) ligand; thiocyanate; triple-stranded chain;

D O I：

10.1016/j.inoche.2004.09.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel cadmium coordination polymer, [Cd-1.5(bbta)(1.5)(NCS)(3)](n) (1) (bbta = 1,2-bis(benzotriazol-1-yl)ethane), possessing the S-bonded octahedral Cd(SCN)(6) and N-bonded octahedral Cd(NCS)(3)(bbta)(3) and unprecedented one-dimensional hetero-triple-stranded chain with alternate two [Cd(NCS)(3)] and one [Cd(bbta)(3)], has been prepared, which exhibits blue luminescent emission at room temperature in the solid state. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1181 / 1183

页数：3