Bioorganometallic chemistry -: Part 15.: A novel molecular recognition process of host, trans-[Cp*Rh(η1(N3)-1-methylcytosine)(μ-OH)]2(OTf)2,with L-aromatic amino acid guests:: selective hydrogen bonding to the μ-OH groups and the 1-methylcytosine ligands

被引：11

作者：

Elduque, A

Carmona, D

Oro, LA

Eisenstein, M

Fish, RH ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, ICMA, Fac Sci,Dept Inorgan Chem, E-50009 Zaragoza, Spain

[2] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

[3] Weizmann Inst Sci, Chem Sci Unit, IL-76100 Rehovot, Israel

[4] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 668卷 / 1-2期

关键词：

molecular recognition; host-guest non-covalent interactions; selective hydrogen bonding;

D O I：

10.1016/S0022-328X(02)02141-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The H-1-NMR and computer docking experiments have elucidated a novel molecular recognition process of host, trans[Cp*Rh(eta(1)(N3)-1-methylcytosine)(mu-OH)](2)(OTf)(2) (1), with L-aromatic amino acids, which is predicated on a selective hydrogen bonding regime of the NH3+ of the amino acid to one of the Rh-mu-OH groups, as well as to a C=O group of one of the other 1-methycytosine ligands, while the COO- H-bonds to an NH2 of the other 1-methycytosine ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：123 / 127

页数：5

共 13 条

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