Quantum control of dissipative systems: Exact solutions

被引:44
作者
Cao, JS
Messina, M
Wilson, KR
机构
[1] Dept. of Chemistry and Biochemistry, University of California, San Diego, San Diego
关键词
D O I
10.1063/1.473522
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Optimal quantum control theory, which predicts the tailored light fields that best drive a system to a desired target, is applied to the quantum dissipative dynamics of systems linearly coupled to a Gaussian bath. To calculate the material response function required for optimizing the light field, the analytical solution is derived for the two-level Brownian harmonic oscillator model and the recently developed method for directly simulating the Gaussian force is implemented for anharmonic Brownian oscillators. This study confirms the feasibility of quantum control in favorable condensed phase environments and explores new quantum control features in the presence of dissipation, including memory effects and temperature dependence. (C) 1997 American Institute of Physics.
引用
收藏
页码:5239 / 5248
页数:10
相关论文
共 48 条
[1]  
APKARIAN VA, 1996, ULTRAFAST PHENOMENA, V10, P219
[2]  
BARDEEN CJ, UNPUB J PHYS CHEM
[3]  
BARDEEN CJ, UNPUB J CHEM PHYS
[4]   TIME-DEPENDENT SOLUTION OF THE LIOUVILLE-VONNEUMANN EQUATION - NONDISSIPATIVE EVOLUTION [J].
BERMAN, M ;
KOSLOFF, R .
COMPUTER PHYSICS COMMUNICATIONS, 1991, 63 (1-3) :1-20
[5]  
BERNE BJ, 1986, ANNU REV PHYS CHEM, V37, P401
[7]   LASER CONTROL OF MOLECULAR PROCESSES [J].
BRUMER, P ;
SHAPIRO, M .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 :257-282
[8]   COHERENT RADIATIVE CONTROL OF UNIMOLECULAR REACTIONS - 3-DIMENSIONAL RESULTS [J].
BRUMER, P ;
SHAPIRO, M .
FARADAY DISCUSSIONS, 1986, 82 :177-185
[9]   QUANTUM TUNNELLING IN A DISSIPATIVE SYSTEM [J].
CALDEIRA, AO ;
LEGGETT, AJ .
ANNALS OF PHYSICS, 1983, 149 (02) :374-456
[10]   SEMICLASSICAL PROPAGATION - PHASE INDEXES AND THE INITIAL-VALUE FORMALISM [J].
CAMPOLIETI, G ;
BRUMER, P .
PHYSICAL REVIEW A, 1994, 50 (02) :997-1018