Single-component molecular metals with extended-TTF dithiolate ligands

被引：418

作者：

Kobayashi, A ^{[1
]}

Fujiwara, E

Kobayashi, H

机构：

[1] Univ Tokyo, Grad Sch Sci, Res Ctr Spectrochem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr030656l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To date, extensive efforts have been devoted to the development of new types of molecular metals and superconductors by enhancing interstack interactions. In designing a single-component molecular metal, the crucial step is the development of a molecule with a small HOMO-LUMO gap and a TTF skeleton. A new idea to reduce the HOMO-LUMO gap is proposed. The scheme is useful for future studies on the bottom-up construction of new functional molecular systems because the properties of the molecular systems are mainly governed by the nature of the frontier orbitals.

引用

页码：5243 / 5264

页数：22