Recent Advances in Enzymatic Fuel Cells: Experiments and Modeling

被引:149
作者
Ivanov, Ivan [2 ]
Vidakovic-Koch, Tanja [1 ]
Sundmacher, Kai [1 ,2 ]
机构
[1] Otto VonGuericke Univ Magdegurg, D-39106 Magdeburg, Germany
[2] Max Planck Inst Dynam Complex Tech Syst, D-39106 Magdeburg, Germany
关键词
biofuel cell; enzymatic electrode; bioelectrocatalysis; modeling; GLUCOSE/O-2 BIOFUEL CELL; DIRECT ELECTRON-TRANSFER; POLYMER-GRAFTED CARBON; MEMBRANE-LESS; AMPEROMETRIC BIOSENSORS; MEDIATED BIOELECTROCATALYSIS; CELLOBIOSE DEHYDROGENASE; PHYSIOLOGICAL CONDITIONS; ADENINE-DINUCLEOTIDE; COMPLETE OXIDATION;
D O I
10.3390/en3040803
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
080707 [能源环境工程]; 082001 [油气井工程];
摘要
Enzymatic fuel cells convert the chemical energy of biofuels into electrical energy. Unlike traditional fuel cell types, which are mainly based on metal catalysts, the enzymatic fuel cells employ enzymes as catalysts. This fuel cell type can be used as an implantable power source for a variety of medical devices used in modern medicine to administer drugs, treat ailments and monitor bodily functions. Some advantages in comparison to conventional fuel cells include a simple fuel cell design and lower cost of the main fuel cell components, however they suffer from severe kinetic limitations mainly due to inefficiency in electron transfer between the enzyme and the electrode surface. In this review article, the major research activities concerned with the enzymatic fuel cells (anode and cathode development, system design, modeling) by highlighting the current problems (low cell voltage, low current density, stability) will be presented.
引用
收藏
页码:803 / 846
页数:44
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