A cationic 1-(2-methylpyridine)phosphole cymene ruthenium chloride complex as an efficient catalyst in the transfer hydrogenation of ketones

被引：68

作者：

Thoumazet, C ^{[1
]}

Melaimi, M ^{[1
]}

Ricard, L ^{[1
]}

Mathey, F ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, Lab Heteroelements & Coordinat, UMR CNRS 7653, Dept Chim, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 08期

关键词：

D O I：

10.1021/om030065l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 2,5-diphenylphospholide anion with 2-chloromethylpyridine affords the 1-(2-methylpyridine)phosphole ligand. The corresponding cationic Ru-(cymene)Cl chelate complex catalyzes the hydrogen transfer process of ketones with very high TON and TOF numbers.

引用

页码：1580 / 1581

页数：2

共 44 条

[1] From regiospecific to regioirregular alternating styrene carbon monoxide copolymerization [J].

Aeby, A ;

Gsponer, A ;

Consiglio, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (42) :11000-11001

[2] Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines [J].

Albrecht, M ;

Crabtree, RH ;

Mata, J ;

Peris, E .

CHEMICAL COMMUNICATIONS, 2002, (01) :32-33

[3] Chelated iridium(III) bis-carbene complexes as air-stable catalysts for transfer hydrogenation [J].

Albrecht, M ;

Miecznikowski, JR ;

Samuel, A ;

Faller, JW ;

Crabtree, RH .

ORGANOMETALLICS, 2002, 21 (17) :3596-3604

[4] COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS [J].

BADER, A ;

LINDNER, E .

COORDINATION CHEMISTRY REVIEWS, 1991, 108 (01) :27-110

[5] A highly selective arene hydrogenation catalyst that operates in ionic liquid [J].

Boxwell, CJ ;

Dyson, PJ ;

Ellis, DJ ;

Welton, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) :9334-9335

[6] Synthesis and structure of Pd(II) complexes containing chelating (phosphinomethyl)oxazoline P,N-type ligands;: copolymerisation of ethylene/CO [J].

Braunstein, P ;

Fryzuk, MD ;

Le Dall, M ;

Naud, F ;

Rettig, SJ ;

Speiser, F .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (07) :1067-1074

[7]

Braunstein P, 2001, ANGEW CHEM INT EDIT, V40, P680, DOI 10.1002/1521-3773(20010216)40:4<680::AID-ANIE6800>3.0.CO

[8]

2-0

[9] A new class of anionic phosphinooxazoline ligands in palladium and ruthenium complexes: catalytic properties for the transfer hydrogenation of acetophenone [J].

Braunstein, P ;

Naud, F ;

Rettig, SJ .

NEW JOURNAL OF CHEMISTRY, 2001, 25 (01) :32-39

[10] 4,5-DIMETHYL-2-(2-PYRIDYL)PHOSPHORIN AS A CHELATING LIGAND - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE ANALYSIS OF (4,5-DIMETHYL-2-(2-PYRIDYL)PHOSPHORIN)TETRACARBONYLCHROMIUM [J].

BREQUE, A ;

SANTINI, CC ;

MATHEY, F ;

FISCHER, J ;

MITSCHLER, A .

INORGANIC CHEMISTRY, 1984, 23 (22) :3463-3467

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