Metallacrown ethers: synthesis and structural investigation of silver metallamacrocycles

被引：20

作者：

Grosshans, P ^{[1
]}

Jouaiti, A ^{[1
]}

Hosseini, MW ^{[1
]}

De Cian, A ^{[1
]}

Kyritsakas-Gruber, N ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Le Bel, F-67000 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 07期

关键词：

metallamacrocycle; pyrazole; silver; metallacrownether; coordination; macrocycle;

D O I：

10.1016/S0040-4039(02)02856-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bis-monodentate ligands 1 and 2 based on the interconnection of two pyrazolyl units by CH2-(CH2-OCH2)(n)-CH2 (n=3 or 4) spacers, respectively, lead to the formation of either mono nuclear silver metallamacrocycle 10 in the case of 1 or binuclear silver metallamacrocycle 1 in the case of 2. Both complexes have been characterised in the solid state by X-ray diffraction on single crystals. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1457 / 1460

页数：4

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