Synthesis, structure and properties of ferrocene functionalized porphyrins

被引：21

作者：

Hodgson, MC

Burrell, AK

Boyd, PDW

Brothers, PJ

Rickard, CEF

机构：

[1] Univ Auckland, Dept Chem, Auckland 1, New Zealand

[2] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2002年 / 6卷 / 11-12期

关键词：

ferrocene; porphyrin; picket fence; metallated;

D O I：

10.1142/S1088424602000853

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of free-base and metallated mixed ferrocenamido- and pivalamidophenylporphyrins have been prepared from the alpha,alpha',alphaalpha",alpha''' isomer of 5,10,15,20-tetra(o-aminophenyl)porphyrin. The X-ray crystal structure of the iron(III) alpha,alpha',alpha",alpha"'-5,10,15,20-tetrakis(o-ferrocenamidophenyl)porphyrin bromide has been determined and compared. with related structures of cobalt(III) alpha,alpha',alpha",alpha'''-5,10,15,20-tetrakis(o-pivalamidophenyl)porphyrin bromide pyridine and the free base alpha,alpha',alpha",alpha'''-5,10,15,20-tetrakis(o-pivalamidophenyl)porphyrin. In both metalloporphyrins the coordinated axial bromides are contained in the cavity formed by the appended pickets with all the amide N-H bonds directed toward the anion. Copyright (C) 2002 Society of Porphyrins & Phthalocyanines.

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页码：737 / 747

页数：11

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