Nickel-catalyzed dehydrative transformation of CO2 to urethanes

被引:53
作者
Abla, M [1 ]
Choi, JC [1 ]
Sakakura, T [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1039/b408429b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ni(OAc)(2)-bipyridine or phenanthroline complexes catalyze the environmentally benign synthesis of urethane from amine, alcohol, and CO2 without toxic and corrosive phosgene; electron-donating and rigid ligands on Ni promote the reaction.
引用
收藏
页码:524 / 525
页数:2
相关论文
共 15 条
[1]   Halogen-free process for the conversion of carbon dioxide to urethanes by homogeneous catalysis [J].
Abla, M ;
Choi, JC ;
Sakakura, T .
CHEMICAL COMMUNICATIONS, 2001, (21) :2238-2239
[2]   Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].
Arakawa, H ;
Aresta, M ;
Armor, JN ;
Barteau, MA ;
Beckman, EJ ;
Bell, AT ;
Bercaw, JE ;
Creutz, C ;
Dinjus, E ;
Dixon, DA ;
Domen, K ;
DuBois, DL ;
Eckert, J ;
Fujita, E ;
Gibson, DH ;
Goddard, WA ;
Goodman, DW ;
Keller, J ;
Kubas, GJ ;
Kung, HH ;
Lyons, JE ;
Manzer, LE ;
Marks, TJ ;
Morokuma, K ;
Nicholas, KM ;
Periana, R ;
Que, L ;
Rostrup-Nielson, J ;
Sachtler, WMH ;
Schmidt, LD ;
Sen, A ;
Somorjai, GA ;
Stair, PC ;
Stults, BR ;
Tumas, W .
CHEMICAL REVIEWS, 2001, 101 (04) :953-996
[3]  
Aresta M, 1997, CHEMTECH, V27, P32
[4]   Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol [J].
Choi, JC ;
He, LN ;
Yasuda, H ;
Sakakura, T .
GREEN CHEMISTRY, 2002, 4 (03) :230-234
[5]   Reaction of dialkyltin methoxide with carbon dioxide relevant to the mechanism of catalytic carbonate synthesis [J].
Choi, JC ;
Sakakura, T ;
Sako, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (15) :3793-3794
[6]   Effects of catalyst phase structure on the elementary processes involved in the synthesis of dimethyl carbonate from methanol and carbon dioxide over zirconia [J].
Jung, KT ;
Bell, AT .
TOPICS IN CATALYSIS, 2002, 20 (1-4) :97-105
[7]   LEWIS-ACID CATALYSIS OF A DIELS-ALDER REACTION IN WATER [J].
OTTO, S ;
ENGBERTS, JBFN .
TETRAHEDRON LETTERS, 1995, 36 (15) :2645-2648
[8]   A systematic study of ligand effects on a Lewis-acid-catalyzed Diels-Alder reaction in water. Water-enhanced enantioselectivity [J].
Otto, S ;
Engberts, JBFN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (29) :6798-6806
[9]   Cationic complexes of palladium(II) and platinum(II) as Lewis acid catalysts for the Diels-Alder reaction [J].
Pignat, K ;
Vallotto, J ;
Pinna, F ;
Strukul, G .
ORGANOMETALLICS, 2000, 19 (24) :5160-5167
[10]   Selective conversion of carbon dioxide to dimethyl carbonate by molecular catalysis [J].
Sakakura, T ;
Saito, Y ;
Okano, M ;
Choi, JC ;
Sako, T .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (20) :7095-7096