Chiral selection on inorganic crystalline surfaces

被引:420
作者
Hazen, RM
Sholl, DS
机构
[1] Carnegie Inst Sci, Washington, DC 20015 USA
[2] NASA, Astrobiol Inst, Washington, DC 20015 USA
[3] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
关键词
D O I
10.1038/nmat879
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
From synthetic drugs to biodegradable plastics to the origin of life, the chiral selection of molecules presents both daunting challenges and significant opportunities in materials science. Among the most promising, yet little explored, avenues for chiral molecular discrimination is adsorption on chiral crystalline surfaces periodic environments that can select, concentrate and possibly even organize molecules into polymers and other macromolecular structures. Here we review experimental and theoretical approaches to chiral selection on inorganic crystalline surfaces-research that is poised to open this new frontier in understanding and exploiting surface-molecule interactions.
引用
收藏
页码:367 / 374
页数:8
相关论文
共 106 条
[41]  
DIELUWEIT SD, 2003, PHYS REV LETT
[42]   SEPARATION OF CHIRAL PHASES IN MONOLAYER CRYSTALS OF RACEMIC AMPHIPHILES [J].
ECKHARDT, CJ ;
PEACHEY, NM ;
SWANSON, DR ;
TAKACS, JM ;
KHAN, MA ;
GONG, X ;
KIM, JH ;
WANG, J ;
UPHAUS, RA .
NATURE, 1993, 362 (6421) :614-616
[43]   Isotopic evidence for extraterrestrial non-racemic amino acids in the Murchison meteorite [J].
Engel, MH ;
Macko, SA .
NATURE, 1997, 389 (6648) :265-268
[44]   The role of quartz in the origin of optical activity on earth [J].
Evgenii, K ;
Wolfram, T .
ORIGINS OF LIFE AND EVOLUTION OF THE BIOSPHERE, 2000, 30 (05) :431-434
[45]   Chiral modification of platinum catalysts by cinchonidine adsorption studied by in situ ATR-IR spectroscopy [J].
Ferri, D ;
Bürgi, T ;
Baiker, A .
CHEMICAL COMMUNICATIONS, 2001, (13) :1172-1173
[46]  
FRONDEL C, 1978, AM MINERAL, V63, P17
[47]   Chiral single crystal surface chemistry [J].
Gellman, AJ ;
Horvath, JD ;
Buelow, MT .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 167 (1-2) :3-11
[48]   Partial dissociation of water molecules in the (3 x 2) water monolayer deposited on the MgO (100) surface [J].
Giordano, L ;
Goniakowski, J ;
Suzanne, J .
PHYSICAL REVIEW LETTERS, 1998, 81 (06) :1271-1273
[49]   Thermal chemistry of H2S and H2O on the (100) plane of pyrite:: Unique reactivity of defect sites [J].
Guevremont, JM ;
Strongin, DR ;
Schoonen, MAA .
AMERICAN MINERALOGIST, 1998, 83 (11-12) :1246-1255
[50]   Noncentrosymmetric oxides [J].
Halasyamani, PS ;
Poeppelmeier, KR .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :2753-2769