Ordered Arrays of Bead-Chain-like In2O3 Nanorods and Their Enhanced Sensing Performance for Formaldehyde

被引：137

作者：

Lai, Xiaoyong ^{[1
]}

Wang, Dan ^{[1
]}

Han, Ning ^{[1
]}

Du, Jiang ^{[1
]}

Li, Jun ^{[1
]}

Xing, Chaojian ^{[1
]}

Chen, Yunfa ^{[1
]}

Li, Xiaotian ^{[2
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China

[2] Jilin Univ, Coll Mat Sci & Engn, Changchun 130012, Peoples R China

来源：

CHEMISTRY OF MATERIALS | 2010年 / 22卷 / 10期

基金：

中国国家自然科学基金;

关键词：

CHEMICAL-VAPOR-DEPOSITION; INDIUM OXIDE; GAS SENSORS; MESOPOROUS SILICA; METAL-OXIDES; NANOCASTING ROUTE; CRYSTALLINE WALLS; FACILE SYNTHESIS; COPPER-OXIDE; NANOPARTICLES;

D O I：

10.1021/cm100181c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Here we present a class of formaldehyde (HCHO) gas sensors with strong responses based on ordered mesostructured In2O3 nanorod arrays, which are synthesized via the nanocastiniz route by directly using the solvent-extracted mesoporous silica as a hard template. By choosing mesoporous silica with different pore sizes and interconnectivity as templates and varying the loading of indium resource on the silica template, we have obtained a series of mesostructured In2O3 nanorod arrays with different textural parameters such as specific surface area, pore size, nanorod diameter, etc. The gas sensing properties for formaldehyde (HCHO) of the In2O3 specimens were examined. The results reveal those mesostructured In2O3 nanorod arrays possess much stronger responses to HCHO even at low concentrations than the bulk In2O3, and larger specific surface areas and pore sizes as well as smaller nanorod diameters would be beneficial for enhancing the sensing properties of In2O3.

引用

页码：3033 / 3042

页数：10

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