Effects of sensitizers on the photodegradation of the systemic fungicide triadimenol

被引：12

作者：

Iesce, MR ^{[1
]}

Graziano, ML ^{[1
]}

Cermola, F ^{[1
]}

Montella, S ^{[1
]}

di Gioia, L ^{[1
]}

Stasio, C ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim Organ & Biochim, I-80126 Naples, Italy

来源：

CHEMOSPHERE | 2003年 / 51卷 / 02期

关键词：

photochemistry; pesticide photodegradation; triadimenol; triadimefon; 9,10-dicyanoanthracene; 2,4,6-triphenylpyrylium tetrafluoroborate;

D O I：

10.1016/S0045-6535(02)00823-8

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The photochemical behaviour of triadimenol (1) under various conditions has been examined. Significant degradation is obtained only in the presence of electron-acceptor sensitizers as 9,10-dicyanoanthracene or 2,4,6-triphenylpyrylium tetrafluoroborate, and long irradiation times are required. 1H-1,2,4-Triazole (2), 4-chlorophenyl formate (3), 4-chlorophenol (4), 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4-triazol-1-yl)butan-2-one (5), 4-chlorophenyl 2,2-dimethylpropanoate (6) and 4-chlorobenzoic acid (7) were identified as photoproducts by NMR and GC-MS. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：163 / 166

页数：4