Syntheses, structures and magnetic behaviors of di- and trinuclear pivalate complexes containing both cobalt(II) and lanthanide(III) ions

被引:42
作者
Cui, Y
Chen, G
Ren, J
Qian, YT [1 ]
Huang, JS
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
D O I
10.1021/ic000230e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The syntheses and X-ray structures of the di- and trinuclear pivalates [C9H7NH][CoTb(Piv)(3)(C9H7N)-(NO3)(3)]. 0.5H(2)O, [CoLn(Piv)(3)(C9H7N)(H2O)]. 0.5C(9)H(7)N (Ln = Gd, Dy), and [Co2Gd(Piv)(6)(C9H7N)(2)(NO3)] (Piv = O2CCMe3) are reported. The four complexes all exhibit weak ferromagnetic interactions between their corresponding heterometallic ions.
引用
收藏
页码:4165 / +
页数:5
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