Photochemistry and reaction intermediates of the bimetallic Group VIII cyclopentadienyl metal carbonyl compounds, (η5-C5H5)2M2(CO)4 and their derivatives

被引：81

作者：

Bitterwolf, TE ^{[1
]}

机构：

[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

关键词：

photochemistry; reaction intermediates; group VIII; cyclopentadienyl metal carbonyl compounds;

D O I：

10.1016/S0010-8545(00)00251-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bonding, structures and photochemistry of the Group VIII metal cyclopentadienyl carbonyl derivatives of the form, (eta(5)-C5H5)(2)M-2(CO)(4), where M = Fe, Ru and Os, are reviewed. The primary emphasis of the review is to bring together the somewhat complex literature in this field, to critically examine the evidence and interpretations and to identify areas for future research opportunities. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：419 / 450

页数：32

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