A twist grain boundary phase with a local antiferroelectric structure

被引:14
作者
Petrenko, AS
Hird, M
Lewis, RA
Meier, JG
Jones, JC
Goodby, JW [1 ]
机构
[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England
[2] Chalmers, Dept Microelect & Nanosci, SE-41296 Gothenburg, Sweden
[3] DERA, Malvern WR14 3PS, Worcs, England
关键词
D O I
10.1088/0953-8984/12/40/303
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
(S)-1-methylheptyl 2-[4-(4-dodecyloxybenzoyloxy)phenyl]pyrimidine-5-carboxylate and its racemic modification were synthesized. Through miscibility studies, investigations of defect textures, differential scanning calorimetry and electrical held studies, we conclude that this material exhibits an antiferroelectric twist grain boundary TGBC(A)* analogue of the Abrikosov flux phase found in superconductors. This outcome represents the addition of a new frustrated state of matter to the family of twist grain boundary phases. This novel phase was found to exist between the isotropic liquid and the antiferroelectric smectic C* phase.
引用
收藏
页码:8577 / 8593
页数:17
相关论文
共 24 条
[21]   MESOGEN EXHIBITING A CH-A-STAR-A PHASE SEQUENCE, A LIQUID-CRYSTALLINE ANALOG OF THE ABRIKOSOV PHASE [J].
SLANEY, AJ ;
GOODBY, JW .
JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (01) :5-10
[22]   THE EFFECT OF MOLECULAR CHIRALITY ON THE INCIDENCE OF TWISTED SMECTIC-A PHASES [J].
SLANEY, AJ ;
GOODBY, JW .
LIQUID CRYSTALS, 1991, 9 (06) :849-861
[23]  
STRAJER G, 1990, PHYS REV LETT, V64, P1545
[24]  
TAKATOH K, UNPUB