Heavy-metal pi complexes .12. A monomeric bis(arene)lead(II) complex with a plumbocene-like bent sandwich structural unit - Structure of [Pb(1,2-C6H4Me2)(2)(AlCl4)(2)]

被引：24

作者：

Frank, W

Wittmer, FG

机构：

[1] Fachbereich Chemie, Universität Kaiserslautern, D-67653 Kaiserslautern

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 12期

关键词：

lead; tetrachloroaluminate; arenes; omicron-xylene; bis(arene) complexes;

D O I：

10.1002/cber.19971301204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(o-xylene)lead(II) bis (tetrachloroaluminate), obtained from lead(II) chloride and aluminium trichloride in o-xylene, has been shown by X-ray crystallography to be a mononuclear lead complex with point group symmetry C-2. The two aromatic ligands are arranged similarly to those in monomeric plumbocene. The coordination sphere is completed by two bidentate AlCl4 ions. The lead center uses about a quarter of its bonding capability for each of the four ligands.

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页码：1731 / 1732

页数：2

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