THE 1ST STRUCTURE OF A SELENANE - METAL(II) COMPLEXES WITH THE 2,4,6-TRIS(TRIFLUOROMETHYL)-SELENOPHENOLATO LIGAND

被引：39

作者：

LABAHN, D ^{[1
]}

BOHNEN, FM ^{[1
]}

HERBSTIRMER, R ^{[1
]}

POHL, E ^{[1
]}

STALKE, D ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 01期

关键词：

SELENANE; BIS(SELENOPHENOLATO)METAL COMPLEXES; CRYSTAL STRUCTURES;

D O I：

10.1002/zaac.19946200107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

R(f)SeH 1 is obtained in a single pot reaction of R(f)Li [R(f) = 2,4,6-tris(trifluoromethyl)phenyl] with elemental seleniun and following treatment with HBF4. 1 gave the first crystal structure of a selenane. Reaction of 1 with M[N(SiMe3)2]2 (M = Zn, Pb) in the molar ratio of 2:1 yielded the metal selenophenolates Zn(SeR(f))2 . HN(SiMe3)2 2 and [Pb(SeRf)2]2 3. 2 crystallizes as hexamethyldisilazane adduct, 3 as a dimer.

引用

页码：41 / 47

页数：7

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