THE 1ST STRUCTURE OF A SELENANE - METAL(II) COMPLEXES WITH THE 2,4,6-TRIS(TRIFLUOROMETHYL)-SELENOPHENOLATO LIGAND

被引：39

作者：

LABAHN, D ^{[1
]}

BOHNEN, FM ^{[1
]}

HERBSTIRMER, R ^{[1
]}

POHL, E ^{[1
]}

STALKE, D ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 01期

关键词：

SELENANE; BIS(SELENOPHENOLATO)METAL COMPLEXES; CRYSTAL STRUCTURES;

D O I：

10.1002/zaac.19946200107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

R(f)SeH 1 is obtained in a single pot reaction of R(f)Li [R(f) = 2,4,6-tris(trifluoromethyl)phenyl] with elemental seleniun and following treatment with HBF4. 1 gave the first crystal structure of a selenane. Reaction of 1 with M[N(SiMe3)2]2 (M = Zn, Pb) in the molar ratio of 2:1 yielded the metal selenophenolates Zn(SeR(f))2 . HN(SiMe3)2 2 and [Pb(SeRf)2]2 3. 2 crystallizes as hexamethyldisilazane adduct, 3 as a dimer.

引用

页码：41 / 47

页数：7

共 34 条

[11]

CRAIG D, 1986, ANGEW CHEM, V98, P178

[12] THE STRUCTURAL CHEMISTRY OF METAL THIOLATE COMPLEXES [J].

DANCE, IG .

POLYHEDRON, 1986, 5 (05) :1037-1104

[13] DISCRETE TRIGONAL-PYRAMIDAL LEAD(II) COMPLEXES - SYNTHESES AND X-RAY STRUCTURE ANALYSES OF [(C6H5)4AS][PB(SC6H5)3] [(C6H5)4AS][PB(SEC6H5)3] [J].

DEAN, PAW ;

VITTAL, JJ ;

PAYNE, NC .

INORGANIC CHEMISTRY, 1984, 23 (25) :4232-4236

[14] DIRECT APPROACHES TO ZINC POLYCHALCOGENIDE CHEMISTRY - ZNS6(N-MEIM)2 AND ZNSE4(N-MEIM)2 [J].

DEV, S ;

RAMLI, E ;

RAUCHFUSS, TB ;

STERN, CL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6385-6386

[15] CRYSTAL HANDLING AT LOW-TEMPERATURES [J].

KOTTKE, T ;

STALKE, D .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 :615-619

[16]

KREBS B, 1989, RINGS CLUSTERS POLYM, P439

[17] PREPARATION AND STRUCTURE OF THALLIUM(I) 2,4,6-TRIS(TRIFLUOROMETHYL)THIOPHENOLATE, A COMPOUND WITH A FOLDED POLYMERIC STRUCTURE [J].

LABAHN, D ;

POHL, E ;

HERBSTIRMER, R ;

STALKE, D ;

ROESKY, HW ;

SHELDRICK, GM .

CHEMISCHE BERICHTE, 1991, 124 (05) :1127-1129

[18] PREPARATION AND STRUCTURES OF MONOMERIC BIS(THIOPHENOLATO)METAL(II) COMPLEXES [J].

LABAHN, D ;

BROOKER, S ;

SHELDRICK, GM ;

ROESKY, HW .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 610 (04) :163-168

[19]

LABAHN D, 1992, THESIS U GOTTINGEN

[20] X-RAY MOLECULAR-STRUCTURES OF [ZN(C3SE5)2]2- AND [ZN(CSE4)2]2- ANION COMPLEXES [J].

MATSUBAYASHI, GE ;

AKIBA, K ;

TANAKA, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (01) :115-119

← 1 2 3 4 →