THE 1ST STRUCTURE OF A SELENANE - METAL(II) COMPLEXES WITH THE 2,4,6-TRIS(TRIFLUOROMETHYL)-SELENOPHENOLATO LIGAND

被引：39

作者：

LABAHN, D ^{[1
]}

BOHNEN, FM ^{[1
]}

HERBSTIRMER, R ^{[1
]}

POHL, E ^{[1
]}

STALKE, D ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 01期

关键词：

SELENANE; BIS(SELENOPHENOLATO)METAL COMPLEXES; CRYSTAL STRUCTURES;

D O I：

10.1002/zaac.19946200107

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

R(f)SeH 1 is obtained in a single pot reaction of R(f)Li [R(f) = 2,4,6-tris(trifluoromethyl)phenyl] with elemental seleniun and following treatment with HBF4. 1 gave the first crystal structure of a selenane. Reaction of 1 with M[N(SiMe3)2]2 (M = Zn, Pb) in the molar ratio of 2:1 yielded the metal selenophenolates Zn(SeR(f))2 . HN(SiMe3)2 2 and [Pb(SeRf)2]2 3. 2 crystallizes as hexamethyldisilazane adduct, 3 as a dimer.

引用

页码：41 / 47

页数：7

共 34 条

[31] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

[32]

SHELDRICK GM, 1992, SHEXL 92 PROGRAMM KR

[33] SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL-LITHIUM.ET2O - A DIMER STABILIZED BY LITHIUM - FLUORINE CONTACTS [J].

STALKE, D ;

WHITMIRE, KH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (11) :833-834

[34] X-RAY STRUCTURES AND FAR-INFRARED AND RAMAN-SPECTRA OF TETRAHEDRAL THIOPHENOLATO AND SELENOPHENOLATO COMPLEXES OF ZINC(II) AND CADMIUM(II) [J].

UEYAMA, N ;

SUGAWARA, T ;

SASAKI, K ;

NAKAMURA, A ;

YAMASHITA, S ;

WAKATSUKI, Y ;

YAMAZAKI, H ;

YASUOKA, N .

INORGANIC CHEMISTRY, 1988, 27 (04) :741-747

← 1 2 3 4 →