Solubility of H2S in (H2O plus piperazine) and in (H2O plus MDEA plus piperazine)

被引：42

作者：

Xia, JZ ^{[1
]}

Kamps, APS ^{[1
]}

Maurer, G ^{[1
]}

机构：

[1] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67653 Kaiserslautern, Germany

来源：

FLUID PHASE EQUILIBRIA | 2003年 / 207卷 / 1-2期

关键词：

gas solubility; sour gas systems; aqueous electrolyte solutions; chemical reacting solutions; hydrogen sulfide; N-methyldiethanolamine; piperazine;

D O I：

10.1016/S0378-3812(02)00331-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New experimental results for the solubility of hydrogen sulfide in aqueous solutions of piperazine are presented for piperazine molalities up to 4 mol/kg of water, temperatures between 313 and 393 K, and pressures up to about 9 MPa. Furthermore, the solubility of hydrogen sulfide was measured in about 2 m MDEA + 2 m piperazine aqueous solutions at 353 K up to about 6 MPa. Considering the new experimental data, a thermodynamic model for describing phase equilibria for the system H2S-methyldiethanolamine-water has been extended allowing for the presence of piperazine. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：23 / 34

页数：12

共 9 条

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