New 3-D chiral framework of indium with 1,3,5-benzenetricarboxylate

被引：153

作者：

Lin, ZZ ^{[1
]}

Jiang, FL ^{[1
]}

Chen, L ^{[1
]}

Yuan, DQ ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 01期

关键词：

D O I：

10.1021/ic0494962

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new complex, [ln(2)(mu-OH)(2)(btc)(2)]n(.)2nHpy (1) (btc = 1,3,5-benzenetricarboxylate; py = pyridine), is hydrothermally synthesized from the reaction of lnCl(3), H(3)btc, and pyridine. Complex 1 crystallizes in the monoclinic P2(1) space group [a = 7.3181(12) Angstrom, b = 17.0195(23) Angstrom, c = 10.5789(17) A, beta = 102.651(6)degrees, and Z = 2]. Indium(III) centers in 1 are bridged by btc ligands in various coordination modes to form the nonclose rings which are further interlinked along crystallographic a-axis and (011) plane to result in a nonpenetrated 3-D anionic framework growing as homochiral tunnels. Compound 1 is fully characterized by fluorescence spectroscopy, second harmonic generation measurement, infrared, and thermogravimetric analysis.

引用

页码：73 / 76

页数：4

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