Three-dimensional silver(I) co-ordination polymer with pocket structures

被引:30
作者
Suenaga, Y [1 ]
Kuroda-Sowa, T
Maekawa, M
Munakata, M
机构
[1] Kinki Univ, Dept Chem, Osaka 5778502, Japan
[2] Kinki Univ, Sci & Technol Res Inst, Osaka 5778502, Japan
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 20期
关键词
D O I
10.1039/b003944f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Silver(I) complexes of hexakis(phenylsulfanyl)benzene (hphb), [Ag-2(hphb)][PF6](2) 1 and [Ag(hphb)(NO3)] 2, have been prepared and their molecular structures determined by X-ray crystallography. In 1 the silver ion adopts a tetrahedral co-ordination geometry comprising four S atoms from two different hphb molecules and giving an eight-membered Ag-S ring structure in a co-ordination polymer. This ring (6.46 x 6.79 Angstrom) forms a three-dimensional framework with pockets. On the other hand, for 2, the silver(I) ion has a square pyramidal environment with four S atoms and one O atom of a NO3- anion. The complex forms a linear-chain structure with an alternating arrangement of silver ions and hphb.
引用
收藏
页码:3620 / 3623
页数:4
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