Multiple-time correlation functions in spin-3/2 solid-state NMR spectroscopy

被引:62
作者
Böhmer, R [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55099 Mainz, Germany
关键词
multipolar spin order; phase cycles; quadrupolar nuclei; stimulated spin echoes;
D O I
10.1006/jmre.2000.2162
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Stimulated echo spectroscopy of nonselectively excitable I = 3/2 nuclei offers new perspectives for the investigation of ultraslow motions predominantly in inorganic solids and solid-like materials. Conditions for the generation of pure, quadrupole modulated multipolar spin orders and for the detection of two- and four-time correlation functions are discussed. The case of spins I > 3/2 is also briefly considered. (C) 2000 Academic Press.
引用
收藏
页码:78 / 88
页数:11
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