New mimic of zeolite: heterometallic organic host framework accommodating inorganic cations

被引：43

作者：

Chen, Yu-Biao ^{[1
]}

Kang, Yao ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 18期

关键词：

COORDINATION POLYMERS; IONOTHERMAL SYNTHESIS; METAL; ZMOFS; STORAGE; DESIGN;

D O I：

10.1039/b927101e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented here is a heterometallic organic framework [Na-2(H2O)(10)](n)[CuZn4(mu(3)-OH)(4)(btec)(2)](n)center dot 2nH(2)O (1, btec = 1,2,4,5-benzenetetracarboxylate) that incorporates mixed Cu2+-Zn2+ oxide chains and accommodates Na+ cations as extraframework guest species; such a building mode is comparable to that of aluminosilicate zeolites where the porous framework combines two kinds of structural building units (such as [SiO4] and [AlO4]) and one kind of inorganic-templating cation.

引用

页码：3182 / 3184

页数：3

共 35 条

[1] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[2]

Batten SR, 2009, COORDINATION POLYMERS: DESIGN, ANALYSIS AND APPLICATION, P1

[3] Syntheses and characterizations of copper(II) polymeric complexes constructed from 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Shi, Q ;

Sun, DF ;

Hong, MC ;

Bi, WH ;

Zhao, YJ .

INORGANIC CHEMISTRY, 2002, 41 (23) :6161-6168

[4] Luminescent open metal sites within a metal-organic framework for sensing small molecules [J].

Chen, Banglin ;

Yang, Yu ;

Zapata, Fatima ;

Lin, Guannan ;

Qian, Guodong ;

Lobkovsky, Emil B. .

ADVANCED MATERIALS, 2007, 19 (13) :1693-+

[5] Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties [J].

Chen, Shumei ;

Zhang, Jian ;

Wu, Tao ;

Feng, Pingyun ;

Bu, Xianhui .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16027-+

[6] Hydrothermal syntheses and structural characterization of zeolite analogue compounds based on cobalt phosphate [J].

Feng, PY ;

Bu, XH ;

Stucky, GD .

NATURE, 1997, 388 (6644) :735-741

[7] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[8]

Flanigen EM., 1991, Studies in Surface Science and Catalysis, V58, P13

[9] Synthesis and structures of new pyromellitate coordination polymers with piperazine as a ligand [J].

Ganesan, SV ;

Natarajan, S .

INORGANIC CHEMISTRY, 2004, 43 (01) :198-205

[10] Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies [J].

Huang, XC ;

Lin, YY ;

Zhang, JP ;

Chen, XM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) :1557-1559

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