CAN-mediated oxidative free radical reactions in an ionic liquid

被引：34

作者：

Bar, G ^{[1
]}

Bini, F ^{[1
]}

Parsons, AF ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 02期

关键词：

radical reactions; ionic liquids;

D O I：

10.1081/SCC-120015703

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cerium(IV) ammonium nitrate-mediated oxidative radical reactions are carried out in the presence of ionic liquids, including 1-butyl-3-methylimidazolium tetrafluoroborate, for the first time. The presence of the ionic liquid not only increases the rate and yield of reactions in dichloromethane but also extends the range of 1,3-dicarbonyl precursors, which can be utilized in these carbon-carbon bond-forming reactions.

引用

页码：213 / 222

页数：10

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