Synthesis of (R)- and (S)-10,16-dihydroxyhexadecanoic acid:: cutin stereochemistry and fungal activation

被引：18

作者：

Ahmed, A

Crawford, T

Gould, S

Ha, YS

Hollrah, M

Noor-E-Ain, F

Dickman, MB

Dussault, PH ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Dept Plant Pathol, Lincoln, NE 68588 USA

来源：

PHYTOCHEMISTRY | 2003年 / 63卷 / 01期

关键词：

tomato; Lycopersicon esculentum; Solonaceae; cutin monomers; DHPA; Colletotrichum trifolii; dihydroxyhexadecanoic acid; asymmetric synthesis;

D O I：

10.1016/S0031-9422(03)00003-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The first asymmetric syntheses of the cutin monomers (R)- and (S)-10,16-dihydroxyhexadecanoic acid (10,16-DHPA) and confirmation of (S)(+)-absolute configuration for 10,16-DHPA derived from tomato are reported. The individual DHPA stereoisomers display differences in their ability to activate the fungal pathogen Colletotrichum trifolii. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：47 / 52

页数：6

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