Surface Fractal dimensionality and hygroscopicity for heated wood

被引:25
作者
Nakano, T [1 ]
Miyazaki, J [1 ]
机构
[1] Hokkaido Forest Prod Res Inst, Asahikawa, Hokkaido 0710198, Japan
关键词
fractal dimensionality; hygroscopicity; heated wood; infrared spectra; adsorption;
D O I
10.1515/HF.2003.043
中图分类号
S7 [林业];
学科分类号
0829 ; 0907 ;
摘要
The relationship between hygroscopicity and the microsurface of heated wood was examined using the fractal surface dimensionality. The hygroscopicity of heated wood decreased with the increase in heating temperature to 250 degreesC, and then decreased again above 350 degreesC after increasing up to 350 degreesC. This change corresponded to chemical changes in the wood, especially a reduction in hydroxyl groups, up to 250 degreesC, and to the temperature dependence of the fractal dimensionality calculated from nitrogen gas adsorption above 250 degreesC. The fractal dimensionality increased gradually from 100 to 250 degreesC, followed by a rapid increase above 250 degreesC with a peak at 350 degreesC, and leveled off above 400 degreesC. From the results, it is concluded that hygroscopicity of heated wood changes at 250 degreesC and that it is dependent upon the chemical properties of wood below 250 degreesC and upon the surface complexity above 250 degreesC.
引用
收藏
页码:289 / 294
页数:6
相关论文
共 35 条
[1]   CHARACTERIZATION AND ANALYSIS OF TORREFIED WOOD [J].
BOURGOIS, J ;
GUYONNET, R .
WOOD SCIENCE AND TECHNOLOGY, 1988, 22 (02) :143-155
[3]   Determination of the surface fractal dimension from sorption isotherms of five softwoods [J].
Fan, K ;
Hatzikiriakos, SG ;
Avramidis, S .
WOOD SCIENCE AND TECHNOLOGY, 1999, 33 (02) :139-149
[4]   SODIUM AZIDE AS AN INTERNAL STANDARD FOR QUANTITATIVE INFRARED ANALYSIS [J].
FRASER, RTM .
ANALYTICAL CHEMISTRY, 1959, 31 (09) :1602-1603
[5]   MULTILAYER PHYSICAL ADSORPTION ON FRACTAL SURFACES [J].
FRIPIAT, JJ ;
GATINEAU, L ;
VANDAMME, H .
LANGMUIR, 1986, 2 (05) :562-567
[6]  
GRAHAMA RG, 1984, J ANAL APPL PYROL, V6, P65
[7]  
Hao BY, 2001, WOOD FIBER SCI, V33, P119
[8]  
HATZIKIRIAKOS SG, 1994, WOOD SCI TECHNOL, V28, P275, DOI 10.1007/BF00204213
[10]  
Hirai N., 1972, Mokuzai Gakkaishi (Journal of the Japan Wood Research Society), V18, P535